As Lotz a Landies has said the engine number is on the passenger side in the middle of the engine behind the exhaust manifold - you will not be able to easily read it though.  The Chassis Number (there is no Vin) is on the front spring hangers but if the ID plate is still in the passenger footwell the numbers are there - as per Ron's photo.  There is no compliance plate on 101s - though if it has been modified there may be relevant plates in the passenger footwell.
If the vehicle is not currently registered then transfer of rego docs are not needed however a receipt will be needed to re-register - if you do not have it you may have to jump through a few hoops.  If the vehicle is still registered then the seller MUST compete the relevant docs - if being difficult I would see the local registration authorities.
Good luck with it.
Garry
				
			 
			
		 
			
				
			
			
				REMLR 243
2007 Range Rover Sport TDV6
1977 FC 101 
1976 Jaguar XJ12C
1973 Haflinger AP700
1971 Jaguar V12 E-Type Series 3 Roadster
1957 Series 1 88"
1957 Series 1 88" Station Wagon
			
			
		 
	
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