Can you lock and unlock the car???
If you can unlock the car open the door, then shut the door and then lock it again and then leave the car for 30mins (to be safe) then unlock and try and start.
if you have left the car unlocked for a length of time they do have a habit of immobilising themselves...the more you try the more it locks the car out.
I had this happen to me had all the usual things done battery disconnect you name it had it towed to the dealer and the bloody thing started on the back of the flat bed at the other end and they drove it off......
This was on my driveway so there was no interference issues...we actaully ended up having the imobiliser replaced as it was too sensitive and kept doing it...never had an issue after that...
a number of people on this forum have had the same issues and I think the people that have, have all owned early defenders like yourself
the unlocking, locking process usually works so hopefully it will work for you (but I'm not sure whether entering a new code changes anything)
Im also assuming your not carrying your second Fob we also found if you have both fobs in the car they some how manage to cancel each other out and also immobilise the car...dont ask me how or why but it does

