Hi Sam,
That's the manual I have, I don't know if it's the one for sale in the "shop" here.
With the timing pins I have, you have to get the engine in just the right spot before inserting them.
From your photos, the crank is half a turn out, the keyway for both the cam drive and the harmonic balancer should be at the top.
The fuel pump is about a quarter of a turn out, the hole for the pin should be about 10-11 o'clock, yours is about 2 o'clock.
Keep in mind the the crank rotates twice for every rotation of the cam and pump.
If you remove the rocker cover, you will, be able to see if the cam is on TDC for number one.
The number one valves will be closed and the rockers will have a small amount of movement, see setting the valve clearance, the first part of the engine section of the manual.
While this will be close, it won't necessarily be correct. I don't know how you set the cam from scratch, it's not in the Defender manual, I assume there is a 300Tdi rebuild manual with more detail.
The 300Tdi is an "interface " motor that is the valves can hit the pistons, this is what happens if you break a cam belt, when this happens you get bent push rods and broken rockers.
So NO DON'T START IT until your happy every thing is timed correctly, also be careful turning it over by hand.
You should check all the push rods and rockers are OK after what has happened.
Here a link to the people who sold the kit in Australia.
YiCaN supply Zeus Timing Gears-eliminates timing belt problems in Land Rover Discovery and Defender. Website:www.yican.com.au
In the menu on the left hand side there is a link to an article fitting the kit.
"LRE Article 06/02"
Is there anything on the cam gear that could be a timing mark? From the article I think the red paint marks are about lining up the gears, rather than timing marks.
Tony