I assume you have an off the shelf unit from one of the NAS manufacturers (if it's one you built yourself I'd be guessing that you'd know what you needed[thumbsupbig]).
If that's the case have a look on their website for a list of manufacturers and drives they support. In principle:
- try to match drives as closely as possible to your existing ones - same model is the perfect solution.
 - if the model is no longer available match one with closest characteristics from the same manufacturer
 - do not use a drive with a smaller capacity than the smallest you have
 - if going larger, generally the NAS will not use additional capacity until all the other smaller drives are replaced with the same or lager capacity ==> wasting your money
 - Don't mix CMR and SMR drives keep it all one way or the other ==> your drives are all CMR (good)
 
In your case I would get a Western Digital Red 
PRO of the same capacity. These are CMR drives so will be the best match for your existing drives. 
Let me know if you have any questions.
EDIT: Actually, you can still get the standard non pro reds with CMR, what size drives do you have?