You have misread the test. The voltage reading should be between the positive terminal of the coil and the negative terminal. Ignition off: zero volts is correct. Ignition on, engine not running, zero volts indicates the amp is not drawing any current through the coil. Any voltage measured here will indicate a failed amp that is drawing permanent current with the ignition on.
To repeat: the voltage should be measured from the positive terminal of the coil across to the negative terminal. Otherwise you are simply testing whether the ignition switch is on or off.
To check the coil out of the vehicle set your meter to ohms, check the resistance across the 2 terminals (primary resistance) somewhere around 0.5 to 1 ohm. Then check from the negative to the main hi voltage terminal (seconday resistance), should be in the Ks of ohms.
For upgrade/repair suggestions look in my thread here:
Lucas ignition amplifier replacement by Bosch 024


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