A pressurised coolant system will get much hotter than 100 degrees.
The TM2 cannot measure the exact temperature of the head as it is mounted externally so the temperature it displays at the sensor is a measure of a number of items but mainly head temperature moderated by other factors - eg heat from the exhaust if nearby making it higher or if in the airflow from the fan a bit lower. The actual temperature displayed is almost irrelevant by itself that is why the instructions do not have an indicative temperature - if I remember correctly they say to drive your vehicle so it gets to operating temperature, note the temperature on the TM2 display and set the alarm at 15 higher.
On my TM2 on my V8, the temp stays at 71 when the engine is running normally and water is 85 but clearly the internal temp of the head will by much hotter. My water temp stays relatively constant where the TM2 can go up to 82 on a hot day idling in traffic - the coolant temp does not change as the thermostat is opening and allowing more coolant through the engine - this is not to say the engine is not actually getting hotting. If you had an oil temp gauge you would most likely find it would be getting hotter as well as the TM2.
So don't worry too much about the temp readout in itself but note the changes in temp - set the TM2 to about 15 hotter than the every day operating temp showing on the TM2.
Garry
REMLR 243
2007 Range Rover Sport TDV6
1977 FC 101
1976 Jaguar XJ12C
1973 Haflinger AP700
1971 Jaguar V12 E-Type Series 3 Roadster
1957 Series 1 88"
1957 Series 1 88" Station Wagon
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