Originally Posted by
JDNSW
While not the first, Romans were the first to widely use a cement made by adding pozzolan to the hydrated lime in their mortar, converting it into a 'hydraulic cement' similar to the modern 'Portland Cement' familiar to us today.
The pozzolan used by the Romans (and today where available) is a naturally occurring volcanic ash, which is in some ways better than what is mostly used because the grains are highly porous, giving a very high surface area and hence highly reactive without being extremely fine grained.
The chemical reaction is basically the same as with modern cements, where the 'pozzolan' component results from the incorporation of siliceous material with the limestone before it is heated. This results in a 'clinker', that is then ground to make the cement. The material used by the Romans did not require the crushing before heating or the grinding afterwards - just needed to be mixed with hydrated lime immediately before use, so a lot less messing about. But there is no significant difference in the final product, or perhaps more accurately, the difference between batches (either type) is more than the difference between the ancient and modern.
John