Actually not quite at right angles - the angle is shown in the workshop manual, although if it is at right angles, it will work OK. This is because, if you think about it, the relay unit turns the left wheel - which means it needs to turn further on left turns than right turns, as the inside wheel has to be turned further.
I agree that a twist on the relay shaft is highly unlikely, and if it has twisted, then failure is imminent.
Other possibilities include a bent drag link or track rod, or it could simply be that the steering stop on one side has moved, or the clamps have come loose and the length of either the track rod or the link from steering box to relay has changed length.
Another thing to check is for a broken centre bolt or main leaf (or a badly worn front bush) in a front or rear spring, allowing the axle to move, so that some steering angle is needed to go straight. A careful look should show this.
John

