Originally Posted by
rick130
Last first.
BITOG was really good once, a number of very clever industry people posted on there but these days there's only a couple I trust, most of the good ones are gone so there's a lot I'd take with a grain of salt. I visit once in a blue moon, but if I have a really important question I pay my money and consult an expert.
One poster there that if you can, read most of what he's written is Molakule. He's very, very clever.
I don't know if Bruce381 still posts, but Bruce is a triboligist too and knows his stuff.
These two blokes blend oils.
Re the metallic ash additives, yes, these are reduced due to Cat's, DPF's, etc but other very good and more expensive additives are often (but not always) substituted. eg tin napthanate's, boron esters, etc.
Shear comes down to the base oils and type of viscosity index improver's used, it's on an oil by oil basis.
A good rule of thumb is that the wider the viscosity spread the greater the tendency to shear, eg a 0W-40 vs a 15W-40 due to the use of viscosity index improver's (VII's) which when added to a base oil reduce the rate at which they thin with increasing temperature. To get a wider spread multi-grade you start with a lower viscosity base oil and add more VII which is why a lot shear in use (and then get thicker later, but that's an oxidative thickening issue and I digress...) but....
base oils like esters have a natural multi-grade characteristic so need less to none VII's compared to a mineral oil. eg Redlines old 15W-40 diesel oil used no VII's at all.
Some VII's (which are polymeric thickeners) can actually mimic a base oil and don't shear in use.
To my knowledge Castrol Europe were the first to use these about ten-fifteen years ago in their premium synthetic oils. They were pretty trick and pretty much blew the Americans minds at the time. I have no idea how widespread their use maybe now.
Re oil coking, oxidising and heat, I wouldn't stress too much between a premium semi-syn and full syn in normal use.
Once upon a time coked up tubo's and turb oil lines was common and full synthetic oils cured that issue, but with a good semi-synthetic meeting modern heavy duty diesel specs it should be a thing of the past.
Remeber that most of the worlds heavy trucks use mineral oils and are heavily turboed and flogged.
It's only when they go to long oil change intervals they use full syn oils, and then they have to do 100,000km on an oil change to make it viable.
Heavy duty diesel oils have higher detergent/dispersant levels than dual grade but petrol biased oils.
Eg Euro ACEA E4/E6/E7/E9 oils or US spec API CI-4+/CJ-4 have higher detegency requirements than ACEA B3/B4 or the old API CF spec, and the later API specs have much tighter wear, oxidative thickening and bore polish limits, among a bunch of other parameters. I haven't read the ACEA ones lately to compare B3/B4 to say, E6 or E9 (E9 being a mid SAPS oil like the API CJ-4, SAPS=Sulpahted Ash, Phosphorous and Sulphur)
This might sound a little disjointed, I have to go, I'm on the road home for the next couple of hours.
cheers.