Your fuel consumption figures are dodgey at best but thats only a base line to work out that there is something unusual going on for you to be getting X amount per litre one tank over a different amount over the next doing the same driving.
I can tell you though, I have a 3.9 Auto Discovery which turns continuous 15/100 on petrol (but only run on petrol on HWY runs) and roughly 18 to 19/100 on LPG around town. and my TDI Auto runs 15/100 pretty much all the time unless on a long run when I get it down into the 12's but I'm running 32's, Steel bar, roof rack and 2" lift pumps tuned for power over economy and EGTs only reach about 660deg max on long uphill stretches.
As far as your starting issue goes, it sounds the same as the Rangie I'm working on for my mate which I'm not really getting anywhere with as yet.
Cheers Casper


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