So update. Went for a drive yesterday (not a common occurrence for me). It was much much cooler outside. Mid-high twenties. Vent temps were typically 6-8 which works. Maybe that isn't so helpful.. if the weather is cool my ac works fine. :(
So while on the trip we were driving back from the desert. I was seeing coolant temps in the mid 100 range, which is higher than I've seen before. It was hot (39 ambient) but still that's pretty hot. I'm thinking first port of call might be to replace the clutch fan. Even if it doesn't help the AC I think that might help engine temps. I spun the fan just then, and when cool there is a lot of resistance. Feels the same hot or cold.
The other thing that might be next on the list. The condenser is showing signs of sitting on the front of a car for 20 years. Corrosion and general deterioration.
Thanks to chat GPT I found this mob which do a parallel flow drop in replacement.
LR025985 - High Performance Air Con Condenser for Land Rover Defender TD5 and Puma 2.4 and 2.2 Vehicles - Air Conditioning Condenser and Fan - by Coolair Logan