Assuming that it is an old Defender, not a new one , all you need are 2 solenoids or big relays triggered by the ignition "on".
I have this setup but with a lead acid starting battery, an AGM and a Lithium and DC/DC charger in my van.
i guess I have an additional wrinkle in that I have a switch fed by my accessory feed to the rear cigarette plug controlling the second relay that enables me to connect the DC/Dc charger to the AGM with IGN off. I haven't used it yet! but maybe one day.
Potential use is solar charging AGM and AGM charging Lithium via DC/DC charger with IGN on ACC and all accessories off.
Works well and has for a couple of years.
Regards PhilipA


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