I,m not a Windows expert, but if the HD is set up as a second disk, and it is booting from the SSD, is there any need to remove anything?  The disc is bootable, but the computer will not even get as far as looking at the boot sector on it, as it will boot from the SSD, assuming this is set as the first boot device. The XP files on it can be simply deleted or just left there as waste space. 
Maybe someone who is more familiar with Windows can say if there is a problem I have not seen.
				
			 
			
		 
			
				
			
			
				John
JDNSW
1986 110 County 3.9 diesel
1970 2a 109 2.25 petrol
			
			
		 
	
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