You are of course theoretically correct.Ethylene Glycol has a lower specific heat than water, so a 50/50 mixture has more trouble carrying away the heat. This mixture is for winter only, I wouldn't run it in warmer weather. Despite your mixture raising the boiling point of the coolant, it gets hotter faster, so you don't want it until the frost sets in.
However Land Rover obviously think that 50/50 is the correct ratio as that is what is stipulated and their cooling systems are sized accordingly.
I have NEVER had an overheat in my RRC with 50/50 and have never in fact had the temp gauge move even to half which is about 105C , even low ranging in 40C plus.
Regards Philip A



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