Probably need to bleed the system.
Don't know about the TD5, but in my 300td D1 refilling the system as follows:
first radiator (which is the lowest point) -close when full
then through the thermostat housing (which is the highest point) with the overflow tank open until coolant is at level in the tank -close tank
then fill up thermostat housing until full.
after this I need to run the engine until warm, turn the heater on and open thermostat housing plug and bleed until no air bubbles (and until heater is warm) - this can take a little while (30min)
Hope this helps.
I also keep an eye on how much coolant I fill in (plus a bit that spills while waiting for the air to escape) so I know how much I am off the total capacity


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