A long-winded update on this - I was sitting around stewing over what could be going wrong, and I thought that maybe there was still a bunch of excess fuel lying around from previous over-rich attempts at starting it.
After a couple of hours of letting it sit, I wound the idle mixture screw to 1.5 turns out. Importantly, I didn't press the accelerator.
It started easily, and ran much better - a little lumpy, but no backfiring and it stayed alive.
While pressing the accelerator pedal for the first time after starting, nice and slowly, it started dying, and lifting off didn't save it.
I let it sit again, then disconnected the accelerator linkage at the carburettor. I got it idling just like before, and tried gently applying some throttle at the carburettor itself - same thing, any throttle at all killed it. Even 10mm of travel. This rules out accelerator linkages/adjustment in my mind, which was a risk because I had to turn two of the levers back to front to reverse the pedal direction when going from the Solex to the Zenith.
I was about to experiment with clamping off the vacuum hose on the hypothesis that ignition timing was out and the vacuum advance when opening the throttle was killing it, when I noticed that the top of the fuel pump was wet. I cranked it over after turning off the ignition, and sure enough there was some sort of leak there.
I've ordered a (Britpart, unfortunately) fuel pump in case the pump itself is causing the leak. It could be the linkages but the current pump is 60 years old, and I was very careful with the linkages to get them tight.
But that's not the end of the story - while putting my hand down the right-hand side of the engine to check said linkages, I bumped the distributor - and the body rotated quite freely. So that's the second thing I need to fix, since timing is probably all out of whack compared to when it was (allegedly) running well with the Zenith.
What a state to get the car back from the mechanic in! At least I have a few things to pursue now, rather than sitting around thinking about it.
Any advice is still welcome, like I said - I'm a newbie.


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