Purchased my first discovery, what should I expect to go wrong first :-)
If you look up from underneath you may be able to trace back to the source of the leak.
Mine has leaks from both head gaskets, each on the outside front corner of the heads. Also check the weep hole on the water pump and check all the hoses.
My money would be on the head gaskets though.... Have you got the gurgling / waterfall sound behind the dash each time you accelerate?
I just checked prices on the 'higher' quality full gasket kits - about £130 from the UK. Service / exchange set of Turner heads are about £580.
Whichever way you cut it, it's going to cost some $$$$.