Certainly in the good old days batteries kept in containers in vehicles had venting to the outside - eg the battery in the engine bay of a Jag Xj12 was contained in a box but it had a 12v fan to provide ventilation.
Gav - as you would be aware the standard 101 battery box is basically sealed but has small flutes cut into its outside to provide ventilation.
I cannot really speak about more modern vehicles like the Defender but I assume there is a vent to the compartment somewhere.
However as discussed above older style lead acid batteries with the caps with vent holes in the caps could give off gas when being charged (my neighbour lost an eye when one blew up) but modern sealed batteries will produce gas when being charged however with a normal rate of charge this is reabsorbed into the fluid and does not vent to atmosphere but all bets are off if there is a problem when charging and the production of gas is too much to be reabsorbed and then it must vent to atmosphere - this is of course hydrogen.
On the thread topic of running cables to the rear - as I have not yet put in an aux battery system, I have a cable that I ran to the rear of my RRS from the main battery - tends to run along cables already on the chassis and in a couple of spots does run inside the chassis - I have already found one spot where a bit of chaffing has occurred from normal driving vibration and thanks to comments about course welds inside the chassis I might have a rethink about the inside the chassis bit.
Cheers
Garry

