Coolant raises the boiling point of the water. So running on water you would have it getting very hot.
Having said that I know a mechanic that after a head gasket replacement would drive for say 150kms on straight water, and then drain and refill with coolant. His reasoning was the coolant ate the head gaskets , the water idea was to condition the head gaskets first. I Don't know about that, but it worked for him.


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