Hi Ron, batteries will “Equalise” ( for want of a better word ).
It doesn’t matter if you have two identical batteries or two totally different batteries, the results will be the same.
If you have a fully charged battery and you connect it, in parallel, to a very discharged battery, say with an SoC ( State of Charge ) of 10%, which is about 11.3 volts, the full battery will discharge into the low battery.
In this extreme case, the low battery will charge slightly but the bulk of the full battery’s charge will, putting simply, be used up by the low battery’s on going chemical reaction.
When ever you apply a voltage to a battery that is higher than the battery’s SoC, there will be a chemical reaction.
If the voltage is less than 1 volt higher than the battery’s SoC, the applied voltage’s energy will do little more than keep the chemical reaction going. ( this is still VERY important )
If the applied voltage is more than one volt above the battery’s SoC, the chemical reaction in the battery will cause the to absorb power. In other words, the battery starts to charge.
So while the full battery’s SoC is more than 1 volt above the low battery’s SoC, some of the current going from the higher to the lower battery will be absorbed as stored power but this will be very little of the capacity coming from the higher charged battery and once the voltage difference is at 1 volt or less, the power coming from the higher charged battery is simply wasted.
The “Equalise” of the two batteries voltage’s will not happen in an instant or even in a few hour but more likely take a few days.
Just some additional info. Where there is an applied voltage of less 1 volt higher than a battery’s SoC, two important things occur,.
1. The battery, while not being charged, it will not discharge either, this is how the float charge cycle of a multi stage battery charger keeps a batter fully charged without over charging it.
2. While any charge ( or discharge ) is occurring, a chemical reaction is occurring in the battery, so a battery will not sulfate, Sulfation is the most common cause of the early demise of stored batteries.
Hope this answers your question!




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