When I did my Libya and Morocco trips I carried 120 Litres of Petrol in the back of my Discovery. For the Libya trip I also carried another 40 litres on the roof rack. The roof rack Jerry Cans were metal and the inside ones were plastic Jerry cans (you should never leave plastic Jerry cans exposed to the sunlight for too long). As Ron says allow room in the can for expansion and it's not a problem.
I also put my 90 upside down in a ditch when I skidded on a roundabout because someone has spilt diesel all over the road
Ivan




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