Don't have a Defender(D1 here), but when I was doing my checks on the tdi, after I fitted a VDO sender(1Gauge gauge), I wanted to be sure of accuracy too.
Measured using an IR thermometer, but using the IR thermometer you can get varying readings all over the motor.
I mainly concentrated on the head area, and found at the thermostat housing(where my sender is located), temps on IR gun was spot on with the VDO sender(and 1Gauge reading).
But I also spot checked various parts of the head, overall at the same temps(~83ish), but some specific spots read over 90C .. whilst at idle most areas(and gauge) read 83C. 
Block I remember was much cooler(more like 60's - 70's) depending where the spot was placed.
				
			 
			
		 
			
				
			
			
				Arthur.
All these discos are giving me a heart attack!
'99 D1 300Tdi Auto ( now sold :( )
'03 D2 Td5 Auto
'03 D2a Td5 Auto
			
			
		 
	
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