Where are the earth connections for the black box alarm? I have seen poor earthing in Defenders cause temp gauges to go right up into the red, when engine isn't actually hot. Did it feel like it was boiling? how much pressure was in the system? The top hose usually won't be full of coolant, expect it to be about half full as it is slightly higher than the coolant bottle. The bubbling may have just been because it was at operating temp. When it was getting hot, was the heater still working? and how is your viscous fan hub?
I am leaning toward an electrical fault still, try adding an extra earth lead from the battery neg to one of the seat box bolts, and see if it still does it.
Sorry for all the questions
JC
The Isuzu 110. Solid and as dependable as a rock, coming soon with auto box😊
The Range Rover L322 4.4.TTDV8 ....probably won't bother with the remap..😈
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