This is quite a normal description of belt squeal. It usually shows up when the engine is cold, with maximum load from the alternator, topping up the battery after having started a cold engine.
The belt will also grip better when it warms up a bit - reducing or eliminating the squeal.
The belt may be dirty or getting worn, or the tensioner may need checking. While the pulley may be a problem, the belt & tensioner are more likely culprits.
Cheers,
Lionel


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