The AGMs in the Thumper would not be the same as Optima because they are special. They are AGM but spiral wound instead of flat panels and much more robust with less problems on corrugations etc.
Bit hard to check the charger because I don't think it will work unless connected to a battery with sufficient voltage to get it going.
Did you notice it being the normal fairly hot temperature that the CTEKs run at or was it cold or really hot? Was the 14V still happening when you disconnected it or just when it started charging?
I would expect that the aux battery would have been feeding high current into the Thumper if it was hot and smelly so check that battery voltage first, if you haven't already. A 7A charger would probably not be able to provide all that much energy to the battery so perhaps it was the other battery that did the damage.
				
			 
			
		 
			
				
			
				
			
			
				Bob
2010 D4 3.0TDV6 SE, ediff, LLAMS, 5 x GOE wheels, LT285/60R18 BFG K02's, GOE Compressor Guard, LR Tank, Mitch Hitch, ECB Bull Bar, Kaymar Rear Bar, Traxide, Safari Snorkel.
2019 Discovery 5 SD6 SE, 20 inch wheels, 275/55R20 Nitto Grappler G2 tyres
			
			
		 
	
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