To fill the pit you need to go back to bare metal. It may be too late to do a cheapie repair as cleaning the pit will be deeper than it looks. Solder is useless, it will melt quite quickly.
Some time ago I rescued a slightly corroded Mercedes 250 head by tapping a small screw into a pitted area after countersinking the thread hole, then shaving the screw head until it tightened up flush with the face. AFAIK the engine is still going 5 years later.
In any case a head face may rescue the surface if you are lucky.


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