A bit of an update on my original post;
One battery (main) was dead flat, the other (aux) was disconnected and after 12 months sitting, still held over 9 volts. 
The main was hooked up to the little ctek for a couple of days (after a few hours on a standard charger), but on reaching the test phase, where it runs up to 14.5v in for a while, then checks to see if it will hold 12v, the battery failed. It is, however, now holding about 5v, so there may be hope for it in the long term.
The aux battery ran on the ctek overnight, and is now on float, with no errors.
I'm planning to let the aux stand alone overnight, to see how it holds up, and put the main back on charge (standard first, then ctek and see how it goes. He's already purchased a replacement main (Yellowtop D34) so if the old battery recovers it'll be kept as a spare.
Thanks for all the advice, folks. It's helped enormously. 
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1999 Disco TD5 ("Bluey")
1996 Disco 300 TDi ("Slo-Mo")
1995 P38A 4.6 HSE ("The Limo")
1966 No 5 Trailer (ARN 173 075) soon to be camper
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