Hmmm..
How long have you had the car?
App 3-4 months
Does the cooling system stay pressurised long after the engine has cooled down?
Yes , I stays Pressuried long after the engine switched off
Is it running rough on startup after being left overnight?
mmm, I'm not
sure about this one , I haven't been inside another Rangie to compare
Is it "using" coolant without having obvious leaks?
Yes , I have to fill up slighty with coolant or water from time to , it seems to drop slightly in cooland level ,but that just may be because the coolant is being pressurised and lost thru the exp tank cap
Can you hear the engine "ticking" periodically, with a repeat pattern ~ once a second when the engine is warm?
yeah I can hear an aweful what sounds like a griding noise may be not so much a ticking periodically coming out from inside the RHS of engine bay area , perhaps from the Tx / gear box but perhaps this may be a different issue all together 
The first three point to a general head gasket / cracked block / slipped liner problem, while the last one is specific to a slipped liner. Another thing you can do is check all your sparks, and if any one looks cleaner than the others, you can bet you've got coolant entering. This is what makes it run rough in the morning - the cooling system pressurises, and the pressure slowly bleeds into the cylinder through a crack / gasket hole / between the liner & cylinder (depending on nature of prblem) and the spark doesn't spark while the cylinder's wet.
Another test is to check your exhaust for excessive liquid spluttering out from cold. Emphasis on excessive, some liquid is normal due to condensation in the pipes.
Ok I will check tomorrow before setting of to do Comp test
I'd say Chemweld is usually there for one reason and one reason only so, while I'd hope its only a blown gasket, I'd secretly be looking for a replacement engine. They're usually not worth fixing if its more serious than a blown head gasket.
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