The plastic dowels DO help locate the head during assembly, but also if the engine gets hot enough, the head WILL walk and even by a fraction of a mm it will break the seal that the head gasket has with the block and head, thereby creating a leak. I wasn't aware you had LPG aswell, the EGT gauge is a MUST have, although LPG is supposed to lower the EGT's under load, it is very important to keep monitoring them as they can still reach epic numbers quite quickly, even on Dieso alone.
45% is a LOT, I would say that is most likely the main cause, and the coolant spewing out means the cap is doing its job and relieving the system of excess pressure due to overheating.
JC
The Isuzu 110. Solid and as dependable as a rock, coming soon with auto box😊
The Range Rover L322 4.4.TTDV8 ....probably won't bother with the remap..😈
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