The camshaft and lifters should be replaced on these engines when rebuilding or looking at them after 100,000km, as they 'float' and the lobes wear out. Mine in a 1987 RR had no lobes left to speak of on two cylinders (passenger side), but it was still running (sort of) ok.
Use a 6 point socket on the cylinder head bolts (ie the socket is against all of the bolt flat), otherwise they will most probably be stripped. Look at the impact wrench sockets, as these are usually 6 points, rather than the more usually 12 points. Due to the expansion rate on these engines, a special loktite is used (272 - high temp , high strength) to ensure that the bolts don't work loose. This makes the force needed to 'crack' them quite a lot. I used a 3/4 adaptor and a length of water pipe and there was a lot of torque required before they let go.
Other than that, its the normal engine rebuild requirements. Ensure adequate oil in the engine before restart, clean out the radiator (back flush etc) when you take it out or get it cleaned professionally, get the cylinder heads done by a professional rebuilder, use quality parts etc.
Look at the items that wear out or deteroriate - water pump, heater hoses etc that are a pain to get to normally and replace these as part of the rebuild.
There is a good website
"RPi Engineering - Specialised Rover Engines" (rpi engineering) that used to give good advice on the rover v8. From recollection,they indicated that the outer bolts on the cyclinder head shouldn't be tightened even to the spec'd torque, as these bolts cause reliability problems. (they may not be on your engine, but they were on mine) However, make your own mind up about this.
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