Originally Posted by 
V8Ian
				 
			I think you're misremembering, Philip. Petrol will ignite at 5% atmospheric mix, which is about the level detectable by humans' noses. A naked flame or spark can certainly and most likely will ignite petrol in the scenario described by you. It would have been explosive, lasting only seconds. A secondary fire of surrounding combustible materials can occur, but the petrol fire would have been exhausted quickly, before the fire brigade arrived. It is unlikely the fellow filling the container would have survived.
The more likely scenario is that the 1,000 litre container was being filled with diesel. Diesel is combustible, not flammable. Although not impossible but highly unlikely, a cigarette will ignite diesel under these circumstances. 
The most likely source of ignition being static electricity. Diesel is highly prone to generating static electricity, while being transferred, which is why it is mandatory to connect an earth strap to the container being filled. 
Your fellow's casual attitude, clearly displayed by his smoking whilst undertaking the task, no doubt saw him fail to earth the vessel.
The combustible diesel burns far slower than petrol and quite conceivably would have been still burning when the fire brigade arrived. Taking into consideration, the time and location of the incident, it would have taken time to extinguish the fire.