from my experience, i have had a fair bit to do with the 300tdi and head gaskets blowing / heating issues,
from your last post saying it takes about 5 mins to start rising, sounds like a blown head gasket (they seem to blow between the number 2 / 3 cyclinder and the water chamber pressureing the chamber,
try running no radiator cap (or leave it on very loose and put some tape over it so it doesnt come off (so the system wont presurise ) and see if it still heaps up and pushes all the fluid out.
also when the a/c is on it creates alot more temperature and blocks the cooling to the radiator by needed the cool air to cool the heat in the a/c..
check to make sure the thermos are working when the a/c is on (there should be 2 approx 10" ones infont of the raidiators which are switched via relays when the a/c is on..
i found mine werent working.


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